Dichlorido(dimethylformamide-κO)[1,4,7-tris(2-cyanoethyl)-1,4,7-triazacyclononane-κ3 N 1,N 4,N 7]cobalt(II)
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چکیده
The title compound, [CoCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], crystallizes as a monomeric complex. The coordination environment around the Co(II) center could be described as a distorted octa-hedron consisting of three N donors from the facially coordinating triaza macrocyclic ligand, one O donor from dimethyl-formamide and two Cl(-) ions. Neutral complex mol-ecules are associated via inter-molecular C-H⋯Cl hydrogen bonds to form two-dimensional layers. C-H⋯O hydrogen bonds are also present.
منابع مشابه
Dichlorido(dimethylformamide-κO)[1,4,7-tris(2-cyanoethyl)-1,4,7-triazacyclononane-κ3 N 1,N 4,N 7]nickel(II)
The title complex, [NiCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], is isomorphous with the Co(II) analogue. Three N-atom donors from the facially coordinating triaza macrocyclic ligand, one O-atom donor from dimethyl-formamide and two Cl(-) anions surround the Ni(II) ion in a distorted octa-hedral coordination geometry. Inter-molecular C-H⋯Cl and C-H⋯N hydrogen-bonding inter-actions link the complex mol...
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